Modelling weathering processes at the catchment scale: The WITCH numerical model     

Yves Goddéris  Louis M. François  Jacques Schott  David Labat 《Geochimica et cosmochimica acta》2006,70(5):1128-1147

A numerical model of chemical weathering in soil horizons and underlying bedrock (WITCH) has been coupled to a numerical model of water and carbon cycles in forest ecosystems (ASPECTS) to simulate the concentration of major species within the soil horizons and the stream of the Strengbach granitic watershed, located in the Vosges Mountains (France). For the first time, simulations of solute concentrations in soil layers and in the catchment river have been performed on a seasonal basis. The model is able to reproduce the concentrations of most major species within the soil horizons, as well as catching the first-order seasonal fluctuations of aqueous calcium, magnesium and silica concentrations. However, the WITCH model underestimates concentrations of Mg²⁺ and silica at the spring of the catchment stream, and significantly underestimates Ca²⁺ concentration. The deficit in calculated calcium can be compensated for by dissolution of trace apatite disseminated in the bedrock. However, the resulting increased Ca²⁺ release yields important smectite precipitation in the deepest model layer (in contact with the bedrock) and subsequent removal of large amount of silica and magnesium from solution. In contrast, the model accurately accounts for the concentrations of major species (Ca, Mg and silica) measured in the catchment stream when precipitation of clay minerals is not allowed. The model underestimation of Mg²⁺ and H₄SiO₄ concentrations when precipitation of well crystallized smectites is allowed strongly suggests that precipitation of well crystallized clay minerals is overestimated and that more soluble poorly crystallized and amorphous materials may be forming. In agreement with observations on other watersheds draining granitic rocks, this study indicates that highly soluble trace calcic phases control the aqueous calcium budget in the Strengbach watershed.  相似文献   

Fault zone geometry of a mature active normal fault: A potential high permeability channel (Pirgaki fault, Corinth rift, Greece)   总被引：2，自引：1，他引：2  

Yves Graud  Marc Diraison  Ney Orellana 《Tectonophysics》2006,426(1-2):61

We present results from petrophysical analysis of a normal fault zone with the aim of defining the flow pathways and their behavior during seismic and interseismic periods. Data are obtained on porosity geometry, strain structure and mineralogy of different domains of a normal fault zone in the Corinth rift. Data point out a close relationship between mineralogy of the clayey minerals, porosity network and strain structures and allow definition of a macroscopic anisotropy of the flow parameters with a strong control by microscopic ultracataclasite structures. The Pirgaki fault zone, developed within pelagic limestone, has a sharp asymmetric porosity profile, with a high porosity volume in the fault core and in the damage zone of the hanging wall. From porosity volumes and threshold measurements, a matrix permeability variation of 6 orders of magnitude could be expected between the protolith and the fault core. Modifications of this pathway during seismic and interseismic phases are depicted. Healing of cracks formed during seismic slip events occurred in the fault core zone and the porous network in the damage zone is sealed in a second step. The lens geometry of the fault core zone is associated with dissolution surfaces and open conduits where dissolved matter could move out of the fault core zone. These elementary processes are developed in particular along Riedel's structures and depend on the orientation of the strain surfaces relative to the local stress and depend also on the roughness of each surface type. P-surfaces are smooth and control shearing process. R-surfaces are rough and present two wavelengths of roughness. The long one controls localization of dissolution surfaces and conduits; the short one is characteristic of dissolution surfaces. The dissolved matter can precipitate in the open structures of the hanging wall damage zone, decreasing the connectivity of the macroscopic conduit developed within this part of the fault zone.  相似文献   

Townsend's Hypothesis, Coherent Structures And Monin–Obukhov Similarity     

K. G. McNaughton  Yves Brunet 《Boundary-Layer Meteorology》2002,102(2):161-175

Townsend's hypothesis states that turbulence near a wall can be divided into an activepart that transports momentum, and an inactive part that does not, and that these twokinds of turbulence do not interact. Active turbulence is generated by wind shear and has properties that scale on local parameters of the flow, while inactive turbulence isthe product of energetic processes remote from the surface and scales on outer-layerparameters. Both kinds of motion can be observed in the atmospheric surface layer, soMonin–Obukhov similarity theory, which is framed in terms of local parameters only,can apply only to active motions. If Townsend's hypothesis were wrong, so that activeand inactive motions do interact in some significant way, then transport processes nearthe ground would be sensitive to outer-layer parameters such as boundary-layer depth,and Monin–Obukhov theory would fail.Experimental results have shown that heat transport near the ground does depend onprocesses in the outer layer. We propose a mechanism for this whereby inactive motionsinitiate active, coherent ejection/sweep structures that carry much of the momentum andheat. We give evidence that the inactive motions take the form of streak patterns of fasterand slower air, and argue that these are induced by the pressure effects of large eddiespassing overhead. The streak pattern includes regions where faster streams of air overtakeand engulf slower-moving streaks. Transverse vortices form across the spines of the streaksat these places and some of them develop into horseshoe vortices. These horseshoe vorticesgrow rapidly and are rotated forward in the sheared flow so they soon contact the ground,squirting the air confined between the legs of the horseshoe vortex outwards as a forcefulejection. This model is consistent with a wide range of results from the field and laboratoryexperiments. Heat transport is significantly affected, so undermining the dimensionalassumptions of Monin–Obukhov similarity theory.  相似文献   

Uniform postglacial slip-rate along the central 600 km of the Kunlun Fault (Tibet), from ²⁶Al, ¹⁰Be, and ¹⁴C dating of riser offsets, and climatic origin of the regional morphology     

Jerome Van Der Woerd  Paul Tapponnier  Frederick J. Ryerson  Anne-Sophie Meriaux  Bertrand Meyer  Yves Gaudemer  Robert C. Finkel  Marc W. Caffee  Zhao Guoguang  Xu Zhiqin 《Geophysical Journal International》2002,148(3):356-388

  相似文献   

Oxydation expérimentale de Fe-tourmalines et corrélation avec une déprotonation des groupes hydroxyleAnnealing in oxidising conditions of Fe-tourmalines and correlated deprotonation of OH groups     

Yves Fuchs  Martine Lagache  Jorge Linares 《Comptes Rendus Geoscience》2002,334(4):245-249

Annealing at 400?T?600 °C (40?P?60 MPa and HM buffer-controlled f(O₂)) of tourmalines synthesised at the same T and P with NNO buffer induces an oxidation of Fe²⁺ into Fe³⁺ in some Y sites only (Mössbauer Spectroscopy data). Annealing in the same conditions of natural tourmalines is consistent with these results. FTIR spectroscopy shows that oxidation of Fe²⁺ into Fe³⁺ is charge-balanced by deprotonation of the external OH₍₃₎ groups. To cite this article: Y. Fuchs et al., C. R. Geoscience 334 (2002) 245–249.  相似文献   

Structure cristalline d'une ménéghinite naturelle pauvre en cuivre,Cu_0,58Pb_12,72(Sb_7,04Bi_0,24)S₂₄Crystal structure of a Cu-poor natural meneghinite,Cu_0.58Pb_12.72(Sb_7.04Bi_0.24)S₂₄     

Yves Moëlo  Pierre Palvadeau  Nicolas Meisser  Alain Meerschaut 《Comptes Rendus Geoscience》2002,334(8):529-536

Cu-poor meneghinite from La Lauzière Massif (Savoy, France) has the composition (electron microprobe) (in wt%): Pb 59.50, Sb 20.33, Bi 1.19, Cu 0.87, Ag 0.05, Fe 0.03, S 17.62, Se 0.05, Total 99.64. Its crystal structure (X-ray on a single crystal) was solved with R1=0.0506, wR2=0.1026, with an orthorhombic symmetry, space group Pnma, and a=24.080(5) Å, b=4.1276(8) Å, c=11.369(2) Å, V=1130.0(4) Å³, Z=4. Relatively to the model of Euler and Hellner (1960), this structure shows a significantly lower site occupancy factor for the tetrahedral Cu site (0.146 against 0.25). Among the five other metallic sites, Bi appears in the one with predominant Sb. Developed structural formula: Cu_0.15Pb₂(Pb_0.53Sb_0.47)(Pb_0.46Sb_0.54)(Sb_0.75Pb_0.19Bi_0.06)S₆; the reduced one: Cu_0.58Pb_12.72(Sb_7.04Bi_0.24)S₂₄. The formation of such a Cu-poor variety seems to be related to specific paragenetic conditions (absence of coexisting galena), or to crystallochemical constraints (minor Bi). To cite this article: Y. Moëlo et al., C. R. Geoscience 334 (2002) 529–536.  相似文献   

Rivers, chemical weathering and Earth's climate   总被引：4，自引：0，他引：4  

Bernard Dupr  Cline Dessert  Priscia Oliva  Yves Goddris  Jrme Viers  Louis Franois  Romain Millot  Jrme Gaillardet 《Comptes Rendus Geoscience》2003,335(16):1141-1160

We detail the results of recent studies describing and quantifying the large-scale chemical weathering of the main types of continental silicate rocks: granites and basalts. These studies aim at establishing chemical weathering laws for these two lithologies, describing the dependence of chemical weathering on environmental parameters, such as climate and mechanical erosion. As shown within this contribution, such mathematical laws are of primary importance for numerical models calculating the evolution of the partial pressure of atmospheric CO₂ and the Earth climate at geological timescales. The major results can be summarized as follow: (1) weathering of continental basaltic lithologies accounts for about 30% of the total consumption of atmospheric CO₂ through weathering of continental silicate rocks. This is related to their high weatherability (about eight times greater than the granite weatherability); (2) a simple weathering law has been established for basaltic lithologies, giving the consumption of atmospheric CO₂ as a function of regional continental runoff, and mean annual regional temperature; (3) no such simple weathering law can be proposed for granitic lithologies, since the effect of temperature can only be identified for regions displaying high continental runoff; (4) a general law relating mechanical erosion and chemical weathering has been validated on small and large catchments. The consequences of these major advances on the climatic evolution of the Earth are discussed. Particularly, the impacts of the onset of the Deccan trapps and the Himalayan orogeny on the global carbon cycle are reinvestigated. To cite this article: B. Dupré et al., C. R. Geoscience 335 (2003).  相似文献   

Nouvelle interprétation structurale de la « faille Nord- Pyrénéenne » en vallée d'Aspe (Pyrénées-Atlantiques). Remise en question d'un plutonisme ophitique danien dans le secteur de Bedous     

Joseph Canérot  Claude Majesté-Menjoulas  Yves Ternet 《Comptes Rendus Geoscience》2004,336(2):135-142

In the Aspe Valley (western Pyrenees), the Europe/Iberia boundary corresponds to a complex fracturing zone, called the ‘Bielle–Accous Wrench-Faulting Corridor’, which represents the classical ‘North-Pyrenean Fault’. Located between the High Primary Range and the North-Pyrenean Zone, the BAWC shows different south-verging sheets mainly composed of Triassic materials. The Bedous ophite, associated with Muschelkalk and Keuper sediments, is also Triassic in age and involved in the same Pyrenean thrusting structures. So, contrary to a recent interpretation, this magmatic rock cannot be related to a supposed Danian plutonism inducing metamorphic processes in the surrounding Mesozoic formations. To cite this article: J. Canérot et al., C. R. Geoscience 336 (2004).  相似文献   

Apparent and real bias in numerical transfer functions in palaeolimnology     

Julien M.J. Racca  Yves T. Prairie 《Journal of Paleolimnology》2004,31(1):117-124

We present an evaluation of the procedure by which model prediction bias is examined in palaeolimnological transfer function inference models. We argue that most of the prediction biases commonly reported in the literature are, in fact, fallacious, and are the artificial consequence of the inappropriate manner in which residuals are traditionally examined. We show that the extent of the specious model bias is entirely predictable from first principles and is essentially determined by the strength of the predictive model. We suggest that the analysis of residuals should always be examined as a function of the model's predictions and we discuss the implications of the old and new approaches.  相似文献   

An automated salt‐tracing gauge for flow‐velocity measurement     

Olivier Planchon  Norbert Silvera  Raphael Gimenez  David Favis‐Mortlock  John Wainwright  Yves Le Bissonnais  Gerard Govers 《地球表面变化过程与地形》2005,30(7):833-844

This article introduces the SVG (salt‐velocity gauge), a novel automated technique for measuring flow velocity by means of salt tracing. SVG allows a high measuring rate (up to one every 2 seconds), short control section length (down to 10 cm), high accuracy (+[sol ]?1·5 cm s^?1), and unbiased calculation of the mean velocity in experimental conditions with turbulent, supercritical flow. A few cubic centimetres of saturated salt solution (NaCl) are injected into the flow at regular time intervals using a programmable solenoid valve. The tracer successively passes two conductivity probes placed a short distance downstream. The transformation of the signal between the two probes is modelled as a one‐dimensional diffusion wave equation. Model calibration gives an estimation of the mean velocity and the diffusion for each salt plume. Two implementations of the SVG technique are described. The first was an outdoors simulated rainfall experiment in Senegal (conductivity probes at 40 cm apart, 8 Hz measurement rate, salt injections at 10 second intervals). Mean velocity was estimated to range between 0·1 and 0·3 m s^?1. The second was a laboratory‐based flume experiment (conductivity probes at 10 cm apart, 32 Hz, salt injections at 2 second intervals). Another SVG with probes at 34 cm apart was used for comparison. An acoustic Doppler velocimeter (ADV) was also used to give an independent assessment of velocity. Using the 10 cm salt gauge, estimated mean velocity ranged from 0·6 to 0·9 m s^?1 with a standard deviation of 1·5 cm s^?1. Comparisons between ADV, 10 cm SVG and 34 cm SVG were consistent and demonstrated that the salt‐tracing results were unbiased and independent of distance between probes. Most peaks were modelled with r² > 90 per cent. The SVG technology offers an alternative to the dye‐tracing technique, which has been severely criticized in the literature because of the wide interval of recommended values for the correction factor α to be applied to the timings. This article demonstrates that a fixed value of α is inappropriate, since the correction factor varies with velocity, diffusion and the length of the control section. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献